Effect of oxidation state on Bi mineral speciation in oxidized and reduced granitoids from the Uetsu region,NE Japan     

Yuya Izumino  Teruyuki Maruoka  Kazuo Nakashima 《Mineralium Deposita》2016,51(5):603-618

  相似文献   

The Cretaceous Ofuku Pluton and Its Relation to Mineralization in the Western Akiyoshi Plateau,Yamaguchi Prefecture,Japan          下载免费PDF全文

Yuka Sasaki  Teruyoshi Imaoka  Mariko Nagashima  Kazuo Nakashima  Takafumi Sonehara  Koshi Yagi  Tetsumaru Itaya 《Resource Geology》2016,66(2):85-113

The relationship between the magmatism of the Cretaceous Ofuku pluton and mineralization in and around the Akiyoshi Plateau, Yamaguchi Prefecture, Japan was investigated using a combination of field observation, petrographic and geochemical analyses, K–Ar geochronology, and fluid inclusion data. The Ofuku pluton has a surface area of 1.5 × 1.0 km, and was intruded into the Paleozoic accretionary complexes of the Akiyoshi Limestone, Ota Group and Tsunemori Formation in the western part of the Akiyoshi Plateau. The pluton belongs to the ilmenite‐series and is zoned, consisting mainly of early tonalite and granodiorite that share a gradational contact, and later granite and aplite that intruded the tonalite and granodiorite. Harker diagrams show that the Ofuku pluton has intermediate to silicic compositions ranging from 60.4 to 77.9 wt.% SiO₂, but a compositional gap exists between 70.5 to 73.4 wt.% SiO₂ (anhydrous basis). Modal and chemical variations indicate that the assumed parental magma is tonalitic. Quantitative models of fractional crystallization based on mass balance calculations and the Rayleigh fractionation model using major and trace element data for all crystalline phases indicate that magmatic fractionation was controlled mainly by crystal fractionation of plagioclase, hornblende, clinopyroxene and orthopyroxene at the early stage, and quartz, plagioclase, biotite, hornblende, apatite, ilmenite and zircon at the later stage. The residual melt extracted from the granodiorite mush was subsequently intruded into the northern and western parts of the Ofuku pluton as melt lens to form the granite and aplite. The age of the pluton was estimated at 99–97 Ma and 101–98 Ma based on K–Ar dating of hornblende and biotite, respectively. Both ages are consistent within analytical error, indicating that the Ofuku pluton and the associated Yamato mine belong to the Tungsten Province of the San‐yo Belt, which is genetically related to the ilmenite‐series granitoids of the Kanmon to Shunan stages. The aplite contains Cl‐rich apatite and REE‐rich monazite‐(Ce), allanite‐(Ce), xenotime and bastnäsite‐(Ce), indicating that the residual melt was rich in halogens and REEs. The tonalite–granodiorite of the Ofuku pluton contains many three‐phase fluid inclusions, along with daughter minerals such as NaCl and KCl, and vapor/liquid (V/L) volume ratios range from 0.2 to 0.9, suggesting that the fluid was boiling. In contrast, the granite and aplite contain low salinity two‐phase inclusions with low V/L ratios. The granodiorite occupies a large part of the pluton, and the inclusions with various V/L ratios with chloride daughter minerals suggest the boiling fluids might be related to the mineralization. This fluid could have carried base metals such as Cu and Zn, forming Cu ore deposits in and around the Ofuku pluton. The occurrence and composition of fluid inclusions in the igneous rocks from the Akiyoshi Plateau are directly linked to Cu mineralization in the area, demonstrating that fluid inclusions are useful indicators of mineralization.  相似文献   

Impact Of The PROCEEDINGS ON THE ANNUAL MEETING OF THE ASSOCIATION OF AMERICAN GEOGRAPHERS: A COMPARISON OF SCIENTIFIC INFORMATION EXCHANGE AT THE 1967 AND 1969 ANNUAL MEETINGS*     

Carnot E. Nelson  Kazuo Tomica 《The Professional geographer》1970,22(4):221-226

  相似文献   

Vertical transport of particulate organic matter in the deep Bering Sea and gulf of Alaska   总被引：1，自引：0，他引：1  

Kazuo Iseki 《Journal of Oceanography》1981,37(3):101-110

Sediment trap arrays were deployed at two deep ocean stations, one in the Bering Sea and the other in the Gulf of Alaska, in the summer of 1975. The sediment trap was constructed of a pair of polyethylene cylinders (0.185 m² opening) with funnel-shaped bases. The trap is equipped with a lid which is closed before recovery by a tripping messenger system triggered by an electric time release. 37–68% of the total organic carbon fluxes (37–38% in the Bering Sea; 48–68% in the Gulf of Alaska) were represented by large particles (67µm<) such as fecal matter and fecal pellets which contributed minor fractions to the total particulate organic matter concentration in sea water. The total fluxes were 11.1 and 14.2 mg C m^–2d^–1 at 1,510 and 2,610 m respectively at the station (3,800 m) in the Bering Sea, and were 7.60, 4.66 and 3.27 mg C m^–2d^–1 at 900, 1,500 and 1,875 m respectively at the station (4,150 m) in the Gulf of Alaska. The former values are several times greater than the latter, suggesting that there is a regional variation in the vertical carbon flux in deep layers. The fluxes were approximately equivalent to 1 to 3% of primary productivity in the overlying surface layers. These observations suggest that deep-water ecosystems may be influenced by relatively rapid sinking of large particles such as fecal matter and fecal pellets from near surface production.  相似文献   

Application of spectral decomposition algorithm for mapping water quality in a turbid lake (Lake Kasumigaura,Japan) from Landsat TM data     

Youichi Oyama  Bunkei Matsushita  Takehiko Fukushima  Kazuo Matsushige  Akio Imai 《ISPRS Journal of Photogrammetry and Remote Sensing》2009,64(1):73-85

The remote sensing of Case 2 water has been far less successful than that of Case 1 water, due mainly to the complex interactions among optically active substances (e.g., phytoplankton, suspended sediments, colored dissolved organic matter, and water) in the former. To address this problem, we developed a spectral decomposition algorithm (SDA), based on a spectral linear mixture modeling approach. Through a tank experiment, we found that the SDA-based models were superior to conventional empirical models (e.g. using single band, band ratio, or arithmetic calculation of band) for accurate estimates of water quality parameters. In this paper, we develop a method for applying the SDA to Landsat-5 TM data on Lake Kasumigaura, a eutrophic lake in Japan characterized by high concentrations of suspended sediment, for mapping chlorophyll-a (Chl-a) and non-phytoplankton suspended sediment (NPSS) distributions. The results show that the SDA-based estimation model can be obtained by a tank experiment. Moreover, by combining this estimation model with satellite-SRSs (standard reflectance spectra: i.e., spectral end-members) derived from bio-optical modeling, we can directly apply the model to a satellite image. The same SDA-based estimation model for Chl-a concentration was applied to two Landsat-5 TM images, one acquired in April 1994 and the other in February 2006. The average Chl-a estimation error between the two was 9.9%, a result that indicates the potential robustness of the SDA-based estimation model. The average estimation error of NPSS concentration from the 2006 Landsat-5 TM image was 15.9%. The key point for successfully applying the SDA-based estimation model to satellite data is the method used to obtain a suitable satellite-SRS for each end-member.  相似文献   

Generation of high resolution sea surface temperature using multi-satellite data for operational oceanography     

YANG Chan-Su  KIM Sun-Hw  OUCHI Kazuo  BACK Ji-Hun 《海洋学报(英文版)》2015,34(7):74-88

In the present article, we introduce a high resolution sea surface temperature(SST) product generated daily by Korea Institute of Ocean Science and Technology(KIOST). The SST product is comprised of four sets of data including eight-hour and daily average SST data of 1 km resolution, and is based on the four infrared(IR) satellite SST data acquired by advanced very high resolution radiometer(AVHRR), Moderate Resolution Imaging Spectroradiometer(MODIS), Multifunctional Transport Satellites-2(MTSAT-2) Imager and Meteorological Imager(MI), two microwave radiometer SSTs acquired by Advanced Microwave Scanning Radiometer 2(AMSR2), and Wind SAT with in-situ temperature data. These input satellite and in-situ SST data are merged by using the optimal interpolation(OI) algorithm. The root-mean-square-errors(RMSEs) of satellite and in-situ data are used as a weighting value in the OI algorithm. As a pilot product, four SST data sets were generated daily from January to December 2013. In the comparison between the SSTs measured by moored buoys and the daily mean KIOST SSTs, the estimated RMSE was 0.71°C and the bias value was –0.08°C. The largest RMSE and bias were 0.86 and –0.26°C respectively, observed at a buoy site in the boundary region of warm and cold waters with increased physical variability in the Sea of Japan/East Sea. Other site near the coasts shows a lower RMSE value of 0.60°C than those at the open waters. To investigate the spatial distributions of SST, the Group for High Resolution Sea Surface Temperature(GHRSST) product was used in the comparison of temperature gradients, and it was shown that the KIOST SST product represents well the water mass structures around the Korean Peninsula. The KIOST SST product generated from both satellite and buoy data is expected to make substantial contribution to the Korea Operational Oceanographic System(KOOS) as an input parameter for data assimilation.  相似文献   

Characteristic of Si:P:N ratio in bottom water in central Suo-Nada,western Seto Inland Sea   总被引：1，自引：0，他引：1  

Kazuo Abe  Mutsumi Tsujino  Norihisa Nakagawa  Katsuyuki Abo 《Journal of Oceanography》2015,71(1):53-63

  相似文献   

Underestimation of nutrient fluxes due to possible bacterial activity during a core incubation experiment   总被引：1，自引：0，他引：1  

Kazuo Abe  Mutsumi Tsujino  Takehiro Kazama  Norihisa Nakagawa  Katsuyuki Abo 《Journal of Oceanography》2015,71(3):263-270

  相似文献   

Ag-Cu-Pb-Bi-S Minerals Newly Discovered from the Ohori Base Metal Deposit, Yamagata Prefecture, NE Japan: Implications for Bi-metallogenesis in the Green-Tuff Region     

Yu Yokoro    Kazuo Nakashima 《Resource Geology》2010,60(1):1-17

The Ohori deposit, one of the base metal deposits in the Green-Tuff region, NE Japan, is composed of two types of mineralization; a skarn-type (Kaninomata orebody) made by the replacement of the Miocene calcareous layer, and a vein-type (Nakanomata orebody). While the ore mineral assemblage of the deposit (chalcopyrite, pyrite, sphalerite and galena) has been known for being rather simple, some Pb-Bi-S minerals have been discovered for the first time in the present study. The minerals mainly occur in the chalcopyrite-rich ores of both orebodies. They essentially belong to the Pb-Bi-S system and contain Cu and Ag in minor amounts, which correspond to the lillianite–gustavite solid solution series (phases Z and X), cosalite, neyite, felbertalite, krupkaite and Bi-bearing galena. The chalcopyrite-rich (Bi-bearing) ores from both orebodies are richer in chalcopyrite, pyrite and chlorite, and have higher homogenization temperatures (>300°C) of fluid inclusions, and higher FeS contents in sphalerite compared to the Bi-free ores. In the Green-Tuff region, Bi-minerals have been reported from many base metal deposits. Most of these Bi-bearing ore deposits are referred to as xenothermal-type deposits, and are characterized by the following common features; composite mineralization of high- and low-temperatures in the shallower environments, and close relationships with the Tertiary granitic rocks. The whole mineralization at the Ohori deposit also has a similar xenothermal character because of the coexistence of high-temperature chalcopyrite-rich ores with Pb-Bi-S minerals, which were formed by the influence of the Tertiary granitic rocks at a shallow depth.  相似文献   

Phase separation,fluid mixing,and origin of the greisens and potassic episyenite associated with the Água Boa pluton,Pitinga tin province,Amazonian Craton,Brazil     

Régis Munhoz Krás Borges  Raimundo Netuno Nobre Villas  Kazuo Fuzikawa  Roberto Dall’Agnol  Marcos Assunção Pimenta 《Journal of South American Earth Sciences》2009,27(2-3):161-183

Based on petrographical data, three types of greisen have been characterized at the western border of Água Boa pluton: siderophyllite–topaz–quartz greisen (greisen 1), fluorite–phengite–quartz greisen (greisen 2) and quartz–chlorite–phengite greisen (greisen 3). Episyenites were also identified.Two fluids of independent origin interacted with the same protolith – a hornblende-biotite alkali feldspar granite – and produced both the greisens and potassic episyenite: (1) an acid, low-salinity (4–12 wt.% NaCl eq.), F-rich, relatively hot (400–350 °C) reduced aqueous-carbonic fluid (CH₄–H₂O–NaCl–FeCl₂ ± KCl), which by immiscibility gave rise to fluid IA (aqueous) and IC (carbonic); and (2) a lower salinity (2–4 wt.% NaCl eq.) and temperature (200–150 °C) aqueous fluid (H₂O–NaCl), which was responsible for all dilution processes. Fluid 1 seems to have had a magmatic-hydrothermal origin, while fluid 2 is probably surface-derived (meteoric water?). An alkaline, F-poorer and diluted equivalent of fluid IA was interpreted to have caused the episyenitization of the granite host rock as well as the formation of phengite-rich greisen 3. The continuos interaction of this fluid with the potassic episyenite produced a moderate- to high-salinity (20–24 wt.% NaCl eq.), low-temperature (200–100 °C) fluid (H₂O–NaCl–CaCl₂ ± KCl), leading to the formation of chlorite-rich zone of greisen 3 and late silicification of potassic episyenite.In the greisen 1, decreasing F-activity and increasing oxygen fugacity, as the system cooled down, favored the formation of a topaz-rich inner zone, which grades into a siderophyllite-rich zone outwardly. Greisen 2 was formed under more oxidizing conditions by fluids poorer in F than those trapped in the siderophyllite-rich zone.The oxidation of aqueous-carbonic fluid took place at three distinct stages: (i) below the FMQ buffer; (ii) between the FMQ and NNO buffers; and (iii) above the NNO buffer.The dissolution cavities generated during the episyenitization process increased the permeability of the altered rocks, resulting in an increase of the fluid/rock ratios at the potassic episyenite and greisen 3 sites.All these fluids were trapped under pressure conditions of <1.0 kbar, representing shallow crustal levels and are consistent with those that have been estimated for the Pitinga tin–granites.The oxygen fugacity, F-activity gradients and salinity variations that occurred during the cooling of the hydrothermal system, in addition to differences in permeability, were important factors in the formation of distinct greisens. They not only controlled the fluid compositional changes, but also caused the cassiterite and sulfide precipitation at the greisen sites.  相似文献